Matias E. Pascualini | Semantic Scholar

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A high-spin square-planar Fe(ii) complex stabilized by a trianionic pincer-type ligand and conclusive evidence for retention of geometry and spin state in solution† †Electronic supplementary…

Matias E. Pascualini, Natali V Di Russo, +5 authors Adam S Veige
Chemical science
2015

Square-planar high-spin Fe(ii) molecular compounds are rare and the only three non-macrocyclic or sterically-driven examples reported share a common FeO4 core. Using an easily modifiable pincer-type… (More)

Evidence for a zwitterionic transition state in double bond rotations within tungsten-vinyl complexes.

Stella A Gonsales, Matias E. Pascualini, Ion Ghiviriga, Adam S Veige
Chemical communications
2015

The trianionic pincer supported tungsten-vinyl complex [CF3-ONO]W(O){(CH3)3CC[double bond, length as m-dash]C(CH3)2} (3syn) undergoes facile double bond rotation at ambient temperature. The… (More)

Solid State Collapse of a High-Spin Square-Planar Fe(II) Complex, Solution Phase Dynamics, and Electronic Structure Characterization of an Fe(II)2 Dimer.

Matias E. Pascualini, Sebastian A Stoian, Andrew Ozarowski, Khalil A Abboud, Adam S Veige
Inorganic chemistry
2016

Square-planar high-spin Fe(II) molecular compounds are rare, and until recently, the only four examples of non-macrocyclic or sterically driven molecular compounds of this kind shared a common FeO4… (More)

Synthesis and characterization of a family of M(2+) complexes supported by a trianionic ONO(3-) pincer-type ligand: towards the stabilization of high-spin square-planar complexes.

Matias E. Pascualini, Sebastian A Stoian, +5 authors Adam S Veige
Dalton transactions
2015

High-spin square-planar molecular compounds are rare. In an effort to access this unique combination of geometry and spin state, we report the synthesis of a series of M(II) compounds stabilized by a… (More)

Synthesis and characterization of trianionic pincer-type complexes of tantalum(V) including solid (X-ray) and solution (NMR) state assignment of an intraligand N–H—F hydrogen bonding interaction

Abstract Tanatalum(V) complexes ligated with a trianionic ONO3− pincer-type ligand were synthesized and characterized. Using the ONO trianionic pincer ligand precursor… (More)

re-planar Fe ( II ) complex stabilized by a trianionic pincer-type ligand and conclusive evidence for retention of geometry and spin state in solution †

Matias E. Pascualini, Natali V. Di Russo, +5 authors Adam S Veige
2014

Square-planar high-spin Fe(II) molecular compounds are rare and the only three non-macrocyclic or sterically-driven examples reported share a common FeO4 core. Using an easily modifiable pincer-type… (More)