Martin Rausch

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The first silenolates with exocyclic structures [(Me 3 Si) 2 Si(Si 2 Me 4) 2 SiC(R)O] − K + (2a: R = 1-adamantyl; 2b: mesityl; 2c: o-tolyl) were synthesized by the reaction of the corresponding acylcyclohexasilanes 1a−c with KOtBu. NMR spectroscopy and single-crystal X-ray diffraction analysis suggest that the aryl-substituted silenolates 2b,c exhibit(More)
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