Markus Joksch

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The synthesis of 3,5-disubstituted cyclometalated iridium(iii) hydrido complexes of the type [3,5-R2(POCOP)IrHX] (3,5-R2(POCOP) = κ3-C5HR2-2,6-(OPtBu2)2 with R = t-Bu, COOMe; X = Cl, H) is described. All complexes were investigated in the catalytic dehydrogenation of hydrazine borane and compared with the unsubstituted compounds [(POCOP)IrHX] (X = Cl, H).(More)
To date, a plethora of λ3 -P nitrogen-containing compounds is known. A large number of them are used as ligands in coordination chemistry and homogeneous catalysis. PN-containing compounds tend to build up cyclic moieties, which have received less attention in regard to their application as ligands in transition metal chemistry. Hence, different(More)
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