Mariya Khiterer

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Water-soluble silsesquioxane nanoparticles (NPs) incorporating viologen groups (PXV; 1,1'-bis[3-(trimethoxysilyl)propyl]-4,4'-bipyridinium iodide) have been synthesized by sol-gel polymerization. The electrochromic properties of the bulk film fabricated by layer-by-layer (LbL) assembly have been examined, along with their incorporation into solid-state(More)
A method for the synthesis of functional hybrid nanoparticles of uniform size is reported. 1,1'-bis[3-(trimethoxysilyl)propyl]-4,4'-bipyridinium iodide and N,N'-bis[(3-trimethoxysilyl)propyl]ethylenediamine bridged polysilsesquioxane spherical, monodisperse nanoparticles are prepared utilizing inverse water-in-oil polymerization methods where nanoparticle(More)
Following its resolution by diastereomeric complexation, 5,5',6,6'-tetrahydroxy-3,3,3',3'-tetramethyl-1,1'-spirobisindane (TTSBI) was used to synthesize a chiral ladder polymer, (+)-PIM-CN. (+)-PIM-COOH was also synthesized by the acid hydrolysis of (+)-PIM-CN. Following characterization, both (+)-PIM-CN and (+)-PIM-COOH were solvent cast directly into(More)
S-oxygenation of dithiocarbamate (DTC) complexes has been implicated in their function as industrial anti-oxidants, as well as in their use as pesticides and most recently in their cumulative toxicity, but little is known of the species generated. Several S-oxygenated derivatives of N,N-disubstituted DTCs have been synthesized, characterized by a variety of(More)
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