Marie-Emmanuelle Boulon

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The [Dy(tta)3(L)] complex behaves as a single ion magnet both in its crystalline phase and in solution. Experimental and theoretical magnetic anisotropy axes perfectly match and lie along the most electro-negative atoms of the coordination sphere. Both VSM and MCD measurements highlight the robustness of the complex, with persistence of the memory effect(More)
The Ce(III) hydrotris(3,5-dimethylpyrazolyl)borate complex [Ce(Tp Me2)2(κ 2-dmpz)] (1) (Tp Me2 = {HB(dmpz)3} − ; dmpz = 3,5-dimethylpyrazolide) was isolated in fair yield from the reaction of [Ce(I)3(THF)4] with two equivalents of [K(Tp Me2)] via the facile decomposition of Tp Me2. [Ce(Tp Me2)2(bipy)] (2) was synthesized in poor yield by the " one-pot "(More)
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