Magnus J Magnussen

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The title compound, mer-[RuCl(3)N(C(18)H(15)As)(2)], is the first structurally characterized example of a nitride complex in which ruthenium is six-coordinated to monodentate ligands only. The Ru[triple-bond]N bond length [1.6161 (15) A] is relatively long, and the trans influence of the nitride ligand is reflected by the difference between the(More)
The first crystal structure of a three-terminal sulfur end-capped oligophenylenevinylene, C36H30O3S3 x 0.5C7H8, has been determined at 122 (1) K. The molecular threefold symmetry is not utilized in the crystal structure. It is confirmed that the double bonds have been fully transformed into a trans configuration by iodine treatment.
Five-coordinate Cr(N)(salen) {salen is 2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolate} reacts with [RhCl(COD)](2) (COD is 1,5-cyclooctadiene) to yield the heterobimetallic nitride-bridged title compound, namely(More)
Amido-bridged dinuclear cobalt(III) complexes with 1,4,7-triazacyclononane (tacn) were synthesized from [Co(tacn)(O3SCF3)3] by treatment with potassium amide in liquid ammonia at 100 degrees C. Two isomeric triply bridged complexes, [(tacn)Co(mu-NH2)3Co(tacn)]3+ and [(tacn)Co(mu-NH2)2[mu-tacn(-H)]Co(NH3)]3+, were isolated as perchlorates, and the crystal(More)
The structures of rac-bis(ethane-1,2-diamine)(oxamato-kappa(2)O(1),O(2))cobalt(III) bis(trifluoromethanesulfonate) dihydrate, [Co(C(2)H(2)NO(3))(C(2)H(8)N(2))(2)](CF(3)SO(3))(2).2H(2)O, (I), and Lambda(+)(578)-bis(ethane-1,2-diamine)[oxamato(2-)-kappa(2)N,O(1)]cobalt(III) trifluoromethanesulfonate, [Co(C(2)HNO(3))(C(2)H(8)N(2))(2)]CF(3)SO(3), (II), are(More)
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