Post-polymerization modification reactions of poly(glycidyl methacrylate)s
- Ezzah M. Muzammil, Anzar Khan, M. Stuparu
- Chemistry, Materials Science
- 7 December 2017
Post-polymerisation modification of poly(glycidyl methacrylate) (PGMA) through the nucleophilic ring opening reactions of the pendent epoxide groups allows for the installation of a variety of…
HYPERELASTIC MATERIAL MODELING
- M. Stuparu
- Engineering
- 2004
Performing a finite element analysis (FEA) on a hyperelastic material is difficult due to nonlinearity, large deformation, and material instability. This paper provides a brief review of the…
Thiol-epoxy “click” chemistry: Application in preparation and postpolymerization modification of polymers
- M. Stuparu, Anzar Khan
- Chemistry
- 1 October 2016
Base-catalyzed reaction between a thiol and an epoxide group is a simple fusion process that leads to the formation of a β-hydroxythio-ether linkage. This reaction is efficient, regio-selective, and…
Dual-Reactive Hyperbranched Polymer Synthesis through Proton Transfer Polymerization of Thiol and Epoxide Groups
- Ikhlas Gadwal, S. Binder, M. Stuparu, Anzar Khan
- Chemistry, Materials Science
- 16 July 2014
A new synthesis of hyperbranched polymers through proton transfer polymerization of thiol and epoxide groups is presented. For this, an AB2 monomer bearing two epoxides and a thiol groups is…
Homopolymer bifunctionalization through sequential thiol–epoxy and esterification reactions: an optimization, quantification, and structural elucidation study
- Ikhlas Gadwal, M. Stuparu, Anzar Khan
- Chemistry
- 10 February 2015
In this study, we probe various aspects of a post-polymerization double-modification strategy involving sequential thiol–epoxy and esterification reactions for the preparation of dual-functional…
Photon Driven Transformation of Cesium Lead Halide Perovskites from Few‐Monolayer Nanoplatelets to Bulk Phase
- Yue Wang, Xiaoming Li, Handong Sun
- PhysicsAdvances in Materials
- 1 December 2016
Benefiting from the remarkable emission color change during PDT, the multicolor luminescence photopatterns and facile information photo-encoding are established.
π-Conjugated Discrete Oligomers Containing Planar and Nonplanar Aromatic Motifs.
- Ji Li, A. Terec, M. Stuparu
- ChemistryJournal of the American Chemical Society
- 21 February 2017
The concept of combining planar and nonplanar aromatic motifs in the design of π-conjugated discrete oligomers is introduced, the synthetic feasibility of such hybrid materials is established, their photophysical properties are reported on, and they are found to be highly active for nonlinear absorption and emission properties.
Corannulene: a molecular bowl of carbon with multifaceted properties and diverse applications.
- Eleni Nestoros, M. Stuparu
- ChemistryChemical Communications
- 19 June 2018
The major synthetic developments in corannulene chemistry which allow the scientific community access to this beautiful molecule in a practical fashion, the unique properties of the corannuene nucleus that sets it apart from the planar polynuclear aromatic hydrocarbons, and its applications in the arena of materials chemistry are discussed.
Structural, optical, and electrochemical properties of three-dimensional push-pull corannulenes.
- Yi-Lin Wu, M. Stuparu, F. Diederich
- ChemistryJournal of Organic Chemistry
- 5 December 2012
NMR, X-ray, and computational studies on 5 and 8 with one cyanobutadienyl substituent suggested the formation of intermolecular corannulene dimers.
Synthesis of corannulene-based nanographenes
- Ezzah M. Muzammil, Dzeneta Halilovic, M. Stuparu
- ChemistryCommunications Chemistry
- 28 May 2019
Corannulene (C20H10) is a polycyclic hydrocarbon in which five six-membered rings surround a central five-membered ring to construct a bowl-like aromatic structure. Here we examine the development of…
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