M. Siegler

Publications363
h-index43
Citations6,674
Highly Influential Citations23
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Discovery of the aggregation pheromone of the brown marmorated stink bug (Halyomorpha halys) through the creation of stereoisomeric libraries of 1-bisabolen-3-ols.
We describe a novel and straightforward route to all stereoisomers of 1,10-bisaboladien-3-ol and 10,11-epoxy-1-bisabolen-3-ol via the rhodium-catalyzed asymmetric addition of trimethylaluminum to…
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Redox Chemistry
Three strikes aN2d you’re out! The spontaneous azide decomposition on mononuclear ruthenium complexes bearing a redox-active aminophenol-derived tridentate NNO ligand selectively generates a rare…
IPr* an easily accessible highly hindered N-heterocyclic carbene.
TLDR
Herein, the efficient three-step synthesis of a novel highly hindered, but flexible, N-heterocyclic carbene and its coordination chemistry to Ag(i) and Rh(i).
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Ketones as directing groups in photocatalytic sp3 C–H fluorination† †Electronic supplementary information (ESI) available. CCDC 1556373, 1556374 and 1556555. For ESI and crystallographic data in CIF…
Visible light-sensitization allows conformationally rigid ketones to act as “directing groups” for aliphatic fluorination using Selectfluor, catalytic benzil, and LEDs.
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Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres
TLDR
Direct evidence for H-bonding is seen in a structural analogue, [FeII(Cl)(N3PyamideSR)](BF4)2 (3).
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Heme/copper assembly mediated nitrite and nitric oxide interconversion.
TLDR
It is shown that a partially reduced heme/Cu assembly reduces NO(2)(-) ion, producing nitric oxide, which serves as the reductant, but the Cu(II) ion is also required.
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Direct, catalytic monofluorination of sp³ C-H bonds: a radical-based mechanism with ionic selectivity.
TLDR
A detailed reaction mechanism based on exhaustive EPR, (19)F NMR, UV-vis, electrochemical, kinetic, synthetic, and computational studies that was revealed to be a radical chain mechanism in which copper acts as an initiator is reported.
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A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity.
TLDR
Comparisons of N4 vs N3S compound reduction potentials provide evidence that (DMA)N3S is a weaker donor to copper ion than is found for any N4 ligand-complex.
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Evidence for a Symmetrical Fluoronium Ion in Solution
TLDR
Chemical and theoretical evidence is presented for the transient generation of a true symmetrical fluoronium ion in solution from an appropriately configured precursor.
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Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent.
At -90 °C in acetone, a stable hydroperoxo complex [(BA)Cu(II)OOH](+) (2) (BA, a tetradentate N(4) ligand possessing a pendant -N(H)CH(2)C(6)H(5) group) is generated by reacting…
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