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Discovery of the aggregation pheromone of the brown marmorated stink bug (Halyomorpha halys) through the creation of stereoisomeric libraries of 1-bisabolen-3-ols.
- A. Khrimian, A. Zhang, T. Leskey
- ChemistryJournal of natural products
- 25 June 2014
We describe a novel and straightforward route to all stereoisomers of 1,10-bisaboladien-3-ol and 10,11-epoxy-1-bisabolen-3-ol via the rhodium-catalyzed asymmetric addition of trimethylaluminum to…
Redox Chemistry
Three strikes aN2d you’re out! The spontaneous azide decomposition on mononuclear ruthenium complexes bearing a redox-active aminophenol-derived tridentate NNO ligand selectively generates a rare…
IPr* an easily accessible highly hindered N-heterocyclic carbene.
- G. Berthon-Gelloz, M. Siegler, A. Spek, B. Tinant, J. Reek, I. Markó
- Chemistry, BiologyDalton transactions
- 26 January 2010
TLDR
Ketones as directing groups in photocatalytic sp3 C–H fluorination† †Electronic supplementary information (ESI) available. CCDC 1556373, 1556374 and 1556555. For ESI and crystallographic data in CIF…
Visible light-sensitization allows conformationally rigid ketones to act as “directing groups” for aliphatic fluorination using Selectfluor, catalytic benzil, and LEDs.
Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres
- L. Widger, C. G. Davies, D. P. Goldberg
- ChemistryJournal of the American Chemical Society
- 28 January 2014
TLDR
Heme/copper assembly mediated nitrite and nitric oxide interconversion.
- S. Hematian, M. Siegler, K. Karlin
- ChemistryJournal of the American Chemical Society
- 6 November 2012
TLDR
Direct, catalytic monofluorination of sp³ C-H bonds: a radical-based mechanism with ionic selectivity.
TLDR
A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity.
- Sunghee Kim, Jung Yoon Lee, K. Karlin
- ChemistryJournal of the American Chemical Society
- 20 February 2015
TLDR
Evidence for a Symmetrical Fluoronium Ion in Solution
- Mark D. Struble, M. Scerba, M. Siegler, T. Lectka
- ChemistryScience
- 5 April 2013
TLDR
Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent.
- Sunghee Kim, C. Saracini, M. Siegler, N. Drichko, K. Karlin
- ChemistryInorganic chemistry
- 15 November 2012
At -90 °C in acetone, a stable hydroperoxo complex [(BA)Cu(II)OOH](+) (2) (BA, a tetradentate N(4) ligand possessing a pendant -N(H)CH(2)C(6)H(5) group) is generated by reacting…
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