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The effect of metal deposition order on the synergistic activity of Au–Cu and Au–Ce metal oxide catalysts for CO oxidation
Abstract Monometallic Au/Al2O3, MxOy/Al2O3 (M Cu; Ce) catalysts and bimetallic catalysts with simultaneously (Au + MxOy) and sequentially (MxOy/Au, Au/MxOy) deposited metals were prepared. OxidationExpand
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Interaction of aluminum and cobalt chlorides and their complexes with propane: A quantum chemical study
Density functional calculations of binary and ternary propane complexes with aluminum and cobalt(II) chlorides were carried out. Interaction of metal chloride complexes with the methylene and methylExpand
  • 3
The effect of H2 treatment at 423–573 K on the structure and synergistic activity of Pd–Cu alloy catalysts for low-temperature CO oxidation
Abstract The effect of H2 treatment at 423–573 K on the structure of Cu/Pd/Al2O3 catalysts for low-temperature CO oxidation was studied by means of XRD, TEM, EDS, FFT, DRIFTS, and XPS methods. TheExpand
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Aluminium Chloride Complexes with Nitrobenzene: Low-Temperature Synthesis, Structure, and Stability
Low-temperature IR spectroscopy was used to study intermolecular interactions in the aluminium chloride–nitrobenzene system. The 1 : 1, 2 : 1, and 1 : 2 molecular complexes of aluminium chloride withExpand
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Reactions of 2-chlorobutane with polynuclear bimetallic aluminum and cobalt chloride complexes: low-temperature synthesis and structure of adducts
Co-condensation of aluminum and cobalt chlorides and 2-chlorobutane leads to the formation of triple complexes. Density functional method PBE was used for the quantum chemical calculations ofExpand
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Propane transformations on aluminum chloride—cobalt chloride clusters: a quantum chemical study
Density functional PBE/TZ2p quantum chemical calculations of activated complexes and pathways of model catalytic transformations of propane under the action of aluminum chloride-cobalt chloride ionicExpand
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Aluminum halide—cobalt halide polynuclear complexes active in low-temperature conversion of alkanes: formation, molecular structures, and IR spectra
Low-temperature FT-IR studies of products of co-condensation of aluminum chloride and cobalt chloride in hydrocarbon matrices were carried out in the temperature range 80–250 K. DFT quantumExpand
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Theoretical and low-temperature IR spectroscopic studies of catalytic complexes of aluminum chloride with nitroalkanes and nitrobenzene
Abstract This paper demonstrates the possibilities and advantages of low-temperature infrared (IR) spectroscopy in investigating active labile catalytic complexes, intermediates, and reactionExpand
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Adsorption and oxidation of carbon monoxide on Au and Ni nanoparticles deposited on Al2O3 by laser electrodispersion
Dissociative adsorption of CO on Au and Ni nanoparticles deposited on Al2O3 by laser electrodispersion (LED) was for the first time observed using diffuse reflectance infrared Fourier transformExpand
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