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Macroeconomic Dynamics and Credit Risk: A Global Perspective
This paper presents a new approach to modeling conditional credit loss distributions. Asset value changes of firms in a credit portfolio are linked to a dynamic global macroeconometric model,Expand
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Natural product-inspired cascade synthesis yields modulators of centrosome integrity.
In biology-oriented synthesis, the scaffolds of biologically relevant compound classes inspire the synthesis of focused compound collections enriched in bioactivity. This criterion is, in particular,Expand
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Biology-oriented synthesis of a natural-product inspired oxepane collection yields a small-molecule activator of the Wnt-pathway
In Biology Oriented Synthesis the scaffolds of biologically relevant compound classes inspire the synthesis of focused compound collections enriched in bioactivity. This criterion is met by theExpand
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Identification of catalytically important residues in the active site of Escherichia coli transaldolase.
The roles of invariant residues at the active site of transaldolase B from Escherichia coli have been probed by site-directed mutagenesis. The mutant enzymes D17A, N35A, E96A, T156A, and S176A wereExpand
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Heteroleptic Organostannylenes and an Organoplumbylene Bearing Phosphorus‐Containing Pincer‐Type Ligands – Structural Variations and Insights into the Configurational Stability
The syntheses of the arylphosphonic esters 3-Br-5-tBu-1-{P(O)(OiPr) 2}C 6H 3 (1), 5-tBu-1,3-{P(O)(OiPr) 2} 2C 6H 3 (2), of the heteroleptic intramolecularly coordinated organostannylenesExpand
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LSn(OCH2CH2)2NR (L = lone pair, W(CO)5; R = Me, t-Bu). The Molecular Structures of 5-Aza-2,8-dioxa-1-stannabicyclo[3.3.0]1.5octanes and Their Tungstenpentacarbonyl Complexes
Single crystal X-ray diffraction analyses of LSn(OCH2CH2)2NR [1, R = Me, L = lone pair; 2, R = Me, L = W(CO)5; 3, R = t-Bu, L = W(CO)5] reveal these compounds to be dimeric and cis-configurated. TheExpand
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Novel Sterically Congested Monoorganobismuth(III) Compounds: Synthesis, Structure, and Bismuth−Arene π Interaction in ArBiXY (X, Y = Br, I, OH, 2,6-Mes2-4-t-Bu-C6H2PHO2)
Four novel sterically congested terphenyl-substituted bismuth dihalides of the type [2,6-Mes2-4-R-C6H2BiX2]2 (1, R = t-Bu, X = Cl, Br; 2, R = H, X = Br; 3, R = t-Bu, X = Br; 4, R = H, X = I) were s...
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Mono-organotin(IV) and tin(IV) derivatives of 2-mercaptopyridine and 2-mercaptopyrimidine: X-ray structures of methyl-tris(2-pyridinethiolato)tin(IV) and
Mono-organotin(IV) and tin(IV) derivatives of 2-mercaptopyridine (HSPy) and 2-mercaptopyrimidine (HSPym), RSnL 3 (R=Me, n-Bu, Ph; L=SPy, SPym; R=Bz=benzyl, o-CIBz, oClC 6 H 4 , p-ClC 6 H 4 , o-tolyl,Expand
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Hydrolysis of Bis((trimethylsilyl)methyl)tin Dihalides. Crystallographic and Spectroscopic Study of the Hydrolysis Pathway
The synthesis and characterization by multinuclear NMR spectroscopy of the diorganotin dihalides (Me3SiCH2)2SnX2 (1, X = Cl; 2, X = Br), the diorganotin dichloride water adduct (Me3SiCH2)2SnCl2·H2OExpand
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