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dâf Heteronuclear complexes: synthesis, structures and physicochemical aspects
Abstract This article concerns d–f heteronuclear complexes, focusing on recent progress in their synthesis, stereochemistry, magnetism, some other physicochemical properties, and potential use as newExpand
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Dinuclear Cobalt(II) Complexes of an Acyclic Phenol‐Based Dinucleating Ligand with Four Methoxyethyl Chelating Arms − First Magnetic Analyses in an Axially Distorted Octahedral Field
An end-off type acyclic ligand with four methoxyethyl chelating arms, 2,6-bis[bis(2-methoxyethyl)aminomethyl]-4-methylphenol [H(bomp)], formed dinuclear cobalt(II) complexes [Co2(bomp)(MeCO2)2]BPh4Expand
  • 85
Dinuclear zinc(II) complex of a new acyclic phenol-based dinucleating ligand with four methoxyethyl chelating arms: first dizinc model with aminopeptidase function
A new end-off type acyclic ligand with four methoxyethyl chelating arms, 2,6-bis[bis(2-methoxyethyl)aminomethyl]-4-methylphenol (Hbomp), formed a dinuclear zinc(II) complex [Zn2(bomp)(MeCO2)2]BPh4 1.Expand
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Ferromagnetic Spin-Coupling in a Binuclear Cu(II)–Gd(III) Complex
Ferromagnetic spin-coupling between Cu(II) and Gd(III) ions was observed in a binuclear Cu(II)–Gd(III) complex CuGd(fsaen)NO3·4H2O (H4fsaen = N,N′-bis(3-carboxysalicylidene)ethylenediamine). TheExpand
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Synthesis, structure, and magnetic properties of discrete d–f heterodinuclear complexes designed from tetrahedrally distorted [Cu(salabza)] (H2salabza = N,N′-bis(salicylidene)-2-aminobenzylamine) and
A tetrahedrally distorted mononuclear copper(II) complex, [Cu(salabza)] 1, and two dinuclear CuLn complexes, [Cu(salabza)Ln(hfac)3] (Ln = Gd 2 or Lu 3), were synthesized and their molecularExpand
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Effect of proton on the catalase-like function of binuclear manganese(iii/iv) complexes with di-μ-oxo bridge
Abstract A binuclear manganese(III/IV) complex, [Mn 2 O 2 (dpa) 2 ] + (Hpda = N,N-bis(2-pyridylmethyl)glycine) exhibited much higher activity for decomposition of hydrogen peroxide than that ofExpand
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Manganese(II) complexes of an acyclic phenol-based dinucleating ligand with four methoxyethyl chelating arms: synthesis, structure, magnetism and electrochemistry
Abstract Dinuclear manganese(II) complexes [Mn 2 (bomp)(PhCO 2 ) 2 ]BPh 4 ( 1 ), [Mn 2 (bomp)(MeCO 2 ) 2 ]BPh 4 ( 2 ), and [Mn 2 (bomp)(PhCO 2 ) 2 ]PF 6 ( 3 ) were synthesized with a dinucleatingExpand
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Ferromagnetic Spin-Coupling between Gadolinium(III) and Copper(II) Ions in Discrete Binuclear Gd(III)–Cu(II) Complexes
Three discrete binuclear gadolinium(III)–copper(II) complexes (CuGd(fsadien)NO3·5H2O (1), CuGd(hsapn)NO3·3H2O (2), and [Gd(pvm)3Cu(A)] (3)) have been synthesized; we use the notationExpand
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Mechanism of LaFeO3 Perovskite-Type Oxide Formation from the Thermal Decomposition of d-f Heteronuclear Complex La[Fe(CN)6]-5H2O
Nanosized, single-phase perovskite-type LaFeO3 powders are synthesized by the thermal decomposition at 600°C of d-f heteronuclear complex La[Fe(CN)6]-5H2O. The mechanism of the formation of LaFeO3Expand
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Synthesis and properties of copper(II)-lanthanide(III) complexes of N,N′-bis(3-formyl-5-methylsalicylidene)-1,3-propanediamine
Abstract Heteronuclear copper(II)-lanthanide(III) complexes of H2(Fsal-3), CuLn(Fsal-3)(NO3)3 (CH3OH)0.5 (Ln: La, Nd, Eu, Gd or Ho), were synthesized and characterized, where H2(Fsal-3) denotesExpand
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