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Pseudopolyanions based on poly(NIPAAM-co-beta-cyclodextrin methacrylate) and ionic liquids.
- Sadik Amajjahe, Soowhan Choi, M. Munteanu, H. Ritter
- Chemistry, Medicine
- Angewandte Chemie
- 21 April 2008
Cyclodextrins (CD) have gained much attention because of their ability to form inclusion complexes in aqueous solutions. Herein we describe the synthesis of cyclodextrincontaining polymers by… Expand
Cyclodextrin Methacrylate via Microwave-Assisted Click Reaction
Click reaction of propargyl methacrylate (1) with 6I-azido-6I-deoxycyclomaltoheptaose (2) was carried out to synthesize mono-(1H-1,2,3-triazol-4-yl)(methyl)2-methylacryl-β-cyclodextrin (3). The… Expand
New Generation of Polymeric Drugs: Copolymer from NIPAAM and Cyclodextrin Methacrylate Containing Supramolecular-Attached Antitumor Derivative†
We describe the synthesis of an adamantane-bearing analogue of 5-fluorocytosine. The process was investigated by 1 H NMR, FT-IR spectroscopy, MS-EI mass spectrometry and elemental analysis. The… Expand
Cyclodextrin-click-cucurbituril: Combi-Receptor for Supramolecular Polymer Systems in Water
We describe the synthesis of a combi-receptor via the click reaction of 6I-azido-6I-deoxycyclomaltoheptaose onto (propargyl-O)6cucurbituril under microwave-assisted conditions. The process was… Expand
Supramolecular Nanocycles Comprising β-Cyclodextrin-click-Ferrocene Units: Rings of Rings of Rings.
We applied 1,3-dipolar cycloaddition to bind ethynylferrocene onto 6I-azido-6I-deoxycyclomaltoheptaose under microwave assisted conditions. The process was investigated by (1) H NMR, FT-IR… Expand
Monoacrylated cyclodextrin via “click” reaction and copolymerization with N-isopropylacrylamide: guest controlled solution properties
Mono-(1 H-1, 2, 3-triazol-4-yl) (methyl) 2-methylacryl-β-cyclodextrin (CD) 3 is synthesized by microwave assisted `click´ reaction of propargyl (meth) acrylate and mono-(6-azido-6-deoxy)-β-CD using… Expand
Supramolecular structures based on dimeric combinations of cyclodextrin and adamantane via click chemistry
We describe the synthesis of 1-mono-β-cyclodextrin-4-[4-(1-mono-β-cyclodextrin-1H-1,2,3-triazol-4-l)butyl]-1H-1,2,3-triazole (CD–CD) 3,… Expand
Switching the Solubility of PMMA Bearing Attached Cyclodextrin-Moieties by Supramolecular Interactions with Ionic Liquids.
- Sadik Amajjahe, M. Munteanu, H. Ritter
- Chemistry, Medicine
- Macromolecular rapid communications
- 2 June 2009
Methacrylate-modified β-cyclodextrin (β-CD) and methyl methacrylate (MMA) have been radically copolymerized to obtain hydrophobic CD copolymers. The water-insoluble copolymers are able to form highly… Expand