Precursors of the RNA World in Space: Detection of (Z)-1,2-ethenediol in the Interstellar Medium, a Key Intermediate in Sugar Formation
- V. Rivilla, L. Colzi, C. Puzzarini
- PhysicsAstrophysical Journal Letters
- 28 March 2022
We present the first detection of (Z)-1,2-ethenediol, (CHOH)2, the enol form of glycolaldehyde, in the interstellar medium toward the G+0.693−0.027 molecular cloud located in the Galactic Center. We…
Rotational and High-resolution Infrared Spectrum of HC3N: Global Ro-vibrational Analysis and Improved Line Catalog for Astrophysical Observations
- L. Bizzocchi, F. Tamassia, R. Garrod
- Physics
- 22 November 2017
HC3N is a ubiquitous molecule in interstellar environments, from external galaxies to Galactic interstellar clouds, star-forming regions, and planetary atmospheres. Observations of its rotational and…
Rotational and Infrared Spectroscopy of Ethanimine: A Route toward Its Astrophysical and Planetary Detection
- A. Melli, M. Melosso, C. Puzzarini
- Physics, Chemistry
- 15 March 2018
Ethanimine, a possible precursor of amino acids, is considered an important prebiotic molecule and thus may play important roles in the formation of biological building blocks in the interstellar…
The GUAPOS project. II. A comprehensive study of peptide-like bond molecules
- L. Colzi, V. Rivilla, L. Kolesnikov'a
- Physics, ChemistryAstronomy & Astrophysics
- 23 July 2021
Peptide-like bond molecules, which can take part to the formation of proteins in a primitive Earth environment, have been detected up to now only towards a few sources. We present a study of HNCO,…
First detection of C2H5NCO in the ISM and search of other isocyanates towards the G+0.693-0.027 molecular cloud
- L. Rodríguez-Almeida, V. Rivilla, J. Martín-Pintado
- ChemistryAstronomy & Astrophysics
- 16 September 2021
Context. Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium (ISM), as only four of them have been detected so far: isocyanate…
First detection of NHD and ND2 in the interstellar medium
- M. Melosso, L. Bizzocchi, P. Caselli
- PhysicsAstronomy & Astrophysics
- 15 July 2020
Context. Deuterium fractionation processes in the interstellar medium (ISM) have been shown to be highly efficient in the family of nitrogen hydrides. To date, observations have been limited to…
An improved rovibrational linelist of formaldehyde, H212C16O
- A. Al-Derzi, J. Tennyson, A. Császár
- Chemistry
- 1 May 2021
Computational molecular spectroscopy
- V. Barone, S. Alessandrini, C. Puzzarini
- ChemistryNature Reviews Methods Primers
- 27 May 2021
The Primer provides essential information about the characteristics, accuracy and limitations of current computational approaches used for modelling spectroscopic phenomena with a focus on estimating error bars, limitations and coupling interpretability to accuracy.
Millimeter-wave and Submillimeter-wave Spectra of Aminoacetonitrile in the Three Lowest Vibrational Excited States
- C. D. Esposti, L. Dore, M. Melosso, Kaori Kobayashi, Chiho Fujita, H. Ozeki
- Chemistry, Physics
- 23 June 2017
It is important to study possible precursors of amino acids such as glycine to enable future searches in interstellar space. Aminoacetonitrile (NH2CH2CN) is one of the most feasible molecules for…
Laboratory measurements and astronomical search for cyanomethanimine.
- M. Melosso, A. Melli, V. Barone
- PhysicsAstronomy & Astrophysics
- 5 December 2017
The combination of the upper limits of the abundances of C-cyanomethanimine together with accurate laboratory frequencies up to ~700 GHz poses the basis for future higher sensitivity searches around Sun-like-star forming regions.
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