M. C. García-Alvarez-Coque

Publications158
h-index33
Citations3,100
Highly Influential Citations47
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Retention mechanisms in micellar liquid chromatography.
Micellar liquid chromatography (MLC) is a reversed-phase liquid chromatographic (RPLC) mode with mobile phases containing a surfactant (ionic or non-ionic) above its critical micellar concentration… Expand
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Analysis of a solute polarity parameter in reversed-phase liquid chromatography on a linear solvation relationship basis
Abstract A study was made to correlate an overall solute polarity descriptor ( p ) with several molecular parameters: excess molar refraction ( E ), dipolarity/polarizability ( S ), effective… Expand
  • 57
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Limits of multi-linear gradient optimisation in reversed-phase liquid chromatography.
The concept of limiting peak purity was applied to quantify the degree of completion of the separation capability of a chromatographic system using multi-linear gradients. The objective was to check… Expand
  • 40
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New Insights and Recent Developments in Micellar Liquid Chromatography
Abstract: Micellar liquid chromatography (MLC) is an efficient alternative to conventional reversed–phase liquid chromatography with hydro‐organic mobile phases. Almost three decades of experience… Expand
  • 84
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Interpretive strategy for optimization of surfactant and alcohol concentration in micellar liquid chromatography
An interpretive procedure for optimization of the retention of the solutes in a mixture, eluted with mobile phases containing a surfactant and an alcohol in micellar liquid chromatography (MLC), is… Expand
  • 61
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The role of the dual nature of ionic liquids in the reversed-phase liquid chromatographic separation of basic drugs.
The cationic nature of basic drugs gives rise to broad asymmetrical chromatographic peaks with conventional C18 columns and hydro-organic mixtures, due to the ionic interaction of the positively… Expand
  • 48
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Gaining insight in the behaviour of imidazolium-based ionic liquids as additives in reversed-phase liquid chromatography for the analysis of basic compounds.
In reversed-phase liquid chromatography in the absence of additives, cationic basic compounds give rise to broad and asymmetrical peaks as a result of ionic interactions with residual free silanols… Expand
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MICELLAR CHROMATOGRAPHIC PROCEDURE WITH DIRECT INJECTION FOR THE DETERMINATION OF SULFONAMIDES IN MILK AND HONEY SAMPLES
The capability of liquid chromatography with micellar mobile phases of sodium dodecyl sulfate (SDS), of allowing the direct injection of biological fluids into reversed-phase columns, was applied to… Expand
  • 29
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Reversed-phase liquid chromatography with mixed micellar mobile phases of Brij-35 and sodium dodecyl sulphate: a method for the analysis of basic compounds
Micellar liquid chromatography (MLC) is a reversed-phase liquid chromatographic (RPLC) mode, which uses a surfactant as a modifier, with significant changes in retention and selectivity with regard… Expand
  • 25
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Reversed-phase liquid chromatography without organic solvent for determination of tricyclic antidepressants.
The chromatographic behavior of seven tricyclic antidepressants (amitryptiline, clomipramine, doxepin, imipramine, maprotiline, nortryptiline, and trimipramine) was examined with micellar mobile… Expand
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