M. Steurer

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Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates are applied in highly enantioselective Diels-Alder and addition reactions, providing functionalized bicyclo[2.2.2]octane compounds and γ'-addition products, respectively. The nature of the transformations and the intermediates involved are(More)
Phosphine-catalyzed [3+2]-cycloaddition reactions of electron deficient allenes and al-kynes with a,b-unsaturated car-bonyl compounds can give access to important highly func-tionalized cyclopentenes. [1] The seminal example of such a transformation was first reported by Lu et al. in 1995, [2] and its asymmetric version in 1997 by the group of Zhang. [3](More)
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