M. M. Rodríguez

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The inherent fault tolerance of artificial neural networks (ANNs) is usually assumed, but several authors have claimed that ANNs are not always fault tolerant and have demonstrated the need to evaluate their robustness by quantitative measures. For this purpose, various alternatives have been proposed. In this paper we show the direct relation between the(More)
The most common catalyst in the Haber-Bosch process for the hydrogenation of dinitrogen (N(2)) to ammonia (NH(3)) is an iron surface promoted with potassium cations (K(+)), but soluble iron complexes have neither reduced the N-N bond of N(2) to nitride (N(3-)) nor produced large amounts of NH(3) from N(2). We report a molecular iron complex that reacts with(More)
Synthetic [2Fe–2S] clusters are often used to elucidate ligand effects on the reduction potentials and spectroscopy of natural electron-transfer sites, which can have anionic Cys ligands or neutral His ligands. Current synthetic routes to [2Fe–2S] clusters are limited in their feasibility with a range of supporting ligands. Here, we report a new synthetic(More)
Metal complexes incorporating the tris(3,5-diphenylpyrazolyl)borate ligand (Tp(Ph2)) and ortho-dihalophenolates were synthesized and characterized in order to explore metal-halogen secondary bonding in biorelevant model complexes. The complexes Tp(Ph2)ML were synthesized and structurally characterized, where M was Fe(II), Co(II), or Ni(II) and L was either(More)
The inherent fault tolerance of artificial neural networks (ANNs) is usually assumed, but several authors have claimed that ANNs are not always fault tolerant and have demonstrated the need to evaluate their robustness by quantitative measures. For this purpose, various alternatives have been proposed. In this paper we show the direct relation between the(More)
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