M. E. Gomez Vara

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In this paper, the kinetics of the thermal decomposition reaction of 3,3,6,6-tetramethyl-1,2,4,5 tetroxane (ACDP) is investigated in various oxygen solvents at different temperatures. Linear relationships are observed between the enthalpy and entropy of activation of the unimolecular reactions of those diperoxides. The isokinetic temperature calculated by(More)
The thermal decomposition reaction of acetone cyclic diperoxide (ACDP) in 1-octanol (OCT) solution, at the temperatures and initial concentration ranges of 130° -166 oC and (0.94-3.00) x 10 mol/L , respectively, follows a pseudo-first order kinetic law. Acetone is the main organic decomposition product observed. The activation parameters values of the(More)
A thermochemical rather simple experimental technique is applied to determine the enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented with suitable theoretical calculations at the semiempirical and ab initio levels. A particular satisfactory agreement between both ways is found for the ab initio calculation at the 6311G basis(More)
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