M. Balaganesh

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The rate coefficients of ((E)-CF(3)CH═CHF, (Z)-CF(3)CH═CHF, (E)-CF(3)CF═CHF, and (Z)-CF(3)CF═CHF) + OH reactions were computed using M06-2X/6-31+G(d,p) theory in the temperature range of 200 and 400 K. The possible reaction mechanisms of the ((E)-CF(3)CH═CHF, (Z)-CF(3)CH═CHF, (E)-CF(3)CF═CHF, and (Z)-CF(3)CF═CHF) + OH reactions were examined. The rate(More)
Nitrate mediated selective oxidation of alkyl aromatics by emulsion electrolysis gives the corresponding carbonyl compounds at moderately high yield (34-84%). The substrate was dissolved in CHCl3 and the aqueous solution consisted of 2% sodium nitrate as a mediator containing a catalytic amount of H2SO4 as supporting electrolyte. The interphasial reaction(More)
The rate coefficient for the gas-phase reaction of Cl atoms with ethyl formate was measured over the temperature range of 268-343 K using relative rate methods, with ethyl chloride as a reference compound. The temperature dependent relative rate coefficients for the ethyl formate + Cl reaction were measured, and the modified Arrhenius expression kethyl(More)
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