M Angeles Alvarez

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The title complex reacted with [Fe2(CO)9] to give the trinuclear derivative [FeW2Cp2(μ-H)(μ-PPh2)(CO)4(NO)2] (W-W = 3.044(1) Å) as a result of full insertion of the 16-electron Fe(CO)4 fragment into the tricentric W-H-W bond of the parent substrate. In contrast, the reactions with the THF adducts [M(CO)5(THF)] (M = W, Mo) and [MnCp'(CO)2(THF)] (Cp' =(More)
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