Luigi Busetto

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The reaction between [Rh[C5H4CO2(CH)2OH](NBD)] (1) and 1,1'-carbonyldiimidazole (CDI) leads to the new CO2-imidazole functionalized alkoxycarbonylcyclopentadienyl complex [Rh[C5H4CO2(CH2)2O2C-Im](NBD)] (2) (Im=imidazole). The latter was treated with five generations of poly(propylenimine) dendrimers DAB-dendr-(NH2)(n) [n=4, 8, 16, 32, 64](More)
The vinyliminium complex [Fe2{mu-eta(1):eta(3)-C(SiMe3)=CHC=N(Me)2}(mu-CO)(CO)(Cp)2][SO3CF3] reacts with HC[triple bond]CR (R = CPh2OH), affording a mixture of the 2,4,6-trisubstituted oxo-eta(5)-cyclohexadienyl complex [Fe{eta(5)-C6H2O(NMe2)(SiMe3)(R)}(Cp)], the 2,6-disubstituted phenol C6H3R(NMe2)OH (R = CHPh2) and 1,2,4-trisubstituted ferrocene(More)
The N-heterocyclic carbene (NHC) precursor, 1-(2-aminoethyl)-3-methylimidazolium nitrate, [NH(2)(CH(2))(2)imMe)]NO(3) ([3][NO(3)]) reacted with Ag(2)CO(3) in dimethyl sulfoxide readily yielding a Ag(I)-(NHC-NH(2)) complex presenting limited stability in solution. The in situ carbene transfer reaction of the latter with [Au(tht)Cl] afforded the first example(More)
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