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Linear polyethylenes in the amorphous region have been simulated as restricted random walks on a diamond lattice between two absorbing planes. The links among loops were studied by treating loops as Ž oriented curves. The local conformations of polyethylene chains i.e., trans and. gauche energy differences were considered in the simulation, thereby… (More)
Polyethylene chains in the amorphous region between two crystalline lamellae M unit apart are modeled as random walks with one-step memory on a cubic lattice between two absorbing boundaries. These walks avoid the two preceding steps, though they are not true self-avoiding walks. Systems of difference equations are introduced to calculate the statistics of… (More)