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Adsorption and desorption of natural organic matter on iron oxide: mechanisms and models.
This study was undertaken to elucidate the interaction mechanism between NOM (natural organic matter) and iron oxide surfaces and to develop a predictive model for NOM adsorption and desorption.Expand
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Byproduct Formation During the Reduction of TCE by Zero‐Valence Iron and Palladized Iron
Trichloroethene (TCE) was reduced with zero-valence iron and palladized iron in zero-head-space extractors. Progress of the reaction in these batch studies was monitored with purge-and-trap gasExpand
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The copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC) “click” reaction and its applications. An overview
Abstract A short overview of the copper(I)-catalyzed azide alkyne cycloaddition (CuAAC), the most used “click” reaction, is presented, including the introduction of the “click” concept, theExpand
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Synthesis of well-defined ABC triblock copolymers with polypeptide segments by ATRP and click reactions
Abstract Well-defined ABC block copolymers consisting of poly(ethylene oxide) monomethylene ether (MPEO) as A block, poly(styrene) (PS) as B block and poly(γ-benzyl- l -glutamate) (PBLG) as C blockExpand
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The Efficient Copper(I) (Hexabenzyl)tren Catalyst and Dendritic Analogues for Green “Click” Reactions between Azides and Alkynes in Organic Solvent and in Water: Positive Dendritic Effects and
An easily synthesized, copper(I) (hexabenzyl)tren complex 1 is an efficient catalyst for the copper(I)-catalyzed Huisgen-type 1,3-cycloaddition between azides and alkynes (CuAAC) reaction in toluene.Expand
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Synthesis of Novel Linear PEO‐b‐PS‐b‐PCL Triblock Copolymers by the Combination of ATRP, ROP, and a Click Reaction
A new strategy to synthesize a series of well-defined amphiphilic PEO-b-PS-b-PCL block copolymers is presented. First, bromine-terminated diblock copolymers PEO-b-PS-Br are prepared by ATRP ofExpand
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Reactions of phosphorus/boron frustrated Lewis pairs with SO2
The frustrated Lewis pair tBu3P/B(C6F5)3 (1) readily adds SO2 to yield the zwitterionic adduct tBu3P+–S(O)–OB−(C6F5)3 (3). A series of intramolecular vicinal P/B FLPs Mes2P–(X)–B(C6F5)2 [X =Expand
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Why Mercury Prefers Soft Ligands
Mercury (Hg) is a major global pollutant arising from both natural and anthropogenic sources. Defining the factors that determine the relative affinities of different ligands for the mercuric ion,Expand
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Cysteine Inhibits Mercury Methylation by Geobacter sulfurreducens PCA Mutant ΔomcBESTZ
Cysteine enhances Hg uptake and methylation by the Geobacter sulfurreducens PCA wild-type (WT) strain in short-term assays. The prevalence of this enhancement in other strains remains poorlyExpand
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Water-soluble glycodendrimers: synthesis and stabilization of catalytically active Pd and Pt nanoparticles
A new water-soluble glycodendrimer containing 9 terminal modified xylose branches was prepared from nona-azide terminated dendrimer by ‘click’ chemistry. The glycodendrimer was analyzed by 1H, 13CExpand
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