Lin-Jiang Shen

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Three ion-pair complexes, [4-NH(2)-Py](2)[M(mnt)(2)] (4-NH(2)-Py(1+)=4-amino-pyridinium; mnt(2-)=maleonitriledithiolate; M=Pt (1), Pd (2) or Ni (3)), have been synthesized and characterized. In the crystal of 1, the strong H-bonding interaction was found from the protonated N-atom of pyridinium to the CN group of [Pt(mnt)(2)](2-) together with a weak Pt...H(More)
In the title compound, C11H8N2O2S, the oxadiazinone ring is nearly planar [maximum deviation = 0.016 (4) Å], and is approximately coplanar with the benzo-thio-phene ring system [dihedral angle = 3.1 (5)°]. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming chains running along the b-axis direction.
A low-dimensional compound [C(6)-Apy][Ni(mnt)(2)] (1, where mnt(2-) = maleonitriledithiolate, C(6)-Apy(+) = 4-amino-1-hexylpyridinium) has been designed and synthesized, which has layer arrangement of anions and cations and shows two steps of magnetic transitions. The low temperature magnetic transition has an uncommon hysteresis loop, while the crystal(More)
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