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A highly lipophilic polyion complex [Pt(en)(2)][PtCl(2)(en)(2)](1)(4) (en, 1,2-diaminoethane) is prepared from one-dimensional mixed valence Pt(II)/Pt(IV) complex and newly designed chiral amphiphile 1. The powdery sample showed purple color, which is a result of the mixed valence absorption of the linear chlorobridged complex (Pt(II)-Cl-Pt(IV)-Cl-)(n).… (More)