Laurence J. Kershaw Cook

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The syntheses of 2,6-di(pyrid-2-yl)pyrazine (L(1)), 2,6-di(pyrazinyl)pyridine (L(2)), 2,2':6',2''-terpyrazine (L(3)), 2,6-di(pyrimidin-4-yl)pyridine (L(4)), 2,6-di(1,2,4-triazin-3-yl)pyridine (L(5)), 4-hydroxy-2,6-di(pyrazinyl)pyridine (L(6)) and 4-hydroxy-2,6-di(pyrimidin-2-yl)pyridine (L(7)) are described. Homoleptic iron(II) and cobalt(II) complexes of(More)
The complex [FeL2][BF4]2 (1; L=4-(isopropylsulfanyl)-2,6-di(pyrazol-1-yl)pyridine) forms solvate crystals 1⋅solv (solv=MeNO2, MeCN, EtCN, or Me2 CO). Most of these materials lose their solvent sluggishly on heating. However, heating 1⋅MeNO2 at 450 K, or storing 1⋅EtCN under ambient conditions, leads to single-crystal to single-crystal exchange of the(More)
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