Larry Werbelow

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Carbon-13 NMR lineshape calculations applicable for deuterated methylene spin groupings are described. The interplay between anisotropic interaction strengths, isotropic couplings, and dynamic parameters are considered in this investigation. It is shown that 13C lineshapes for this system are informative and provide details on numerous factors that are(More)
In practice, many situations arise when a perturbed nuclear spin relies upon the aid of a rapidly relaxed spin neighbor in order to realize thermal equilibrium. Conventional treatments view the efficiently relaxed spin as part of the 'lattice', invoke the secular approximation, and consider the associated time correlation of the lattice variables,(More)
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