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Exploring the photoexcited triplet states of aluminum and tin corroles by time-resolved Q-band EPR
The photoexcited triplet states of three 5,10, 15-tris(pentafluorophenyl)corroles (tpfc), hosting Sn(IV) and Al(III) in their core, namely, Sn(Cl)(tpfc), Al(pyr)2(tpfc) and Al(pyr)2(tpfc-Br8), wereExpand
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Electronic Structures and Reactivities of Corrole−Copper Complexes
The spectroscopic and electrochemical examination of the mononuclear copper complexes of 5,10,15-tris(pentafluorophenyl)corrole and 5,10,15-tris(2,6-dichlorophenyl)corrole (1a and 2a, respectively)Expand
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Synthesis, spectroscopy, and structures of new rhodium(I) and rhodium(III) corroles and catalysis thereby
The syntheses and molecular structures of six- and five-coordinated rhodium(III) corroles (by pyridines and a chiral amine, respectively) and the rhodium(I) complex of a chiral corrole are described,Expand
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The effects of bulky ortho-aryl substituents in corroles, tested by X-ray crystallography of the rhodium complexes and catalysis thereby
In the present publication we report on the preparation and spectroscopic features of a penta-coordinate rhodium(III) complex of corrole with bulky ortho-phenyl substituents at the meso positions,Expand
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Synthesis and characterization of germanium, tin, phosphorus, iron, and rhodium complexes of tris(pentafluorophenyl)corrole, and the utilization of the iron and rhodium corroles as cyclopropanation
The germanium(IV), tin(IV). and phosphorus(v) complexes of tris(pentafluorophenyl)corrole were prepared and investigated by electrochemistry for elucidation of the electrochemical HOMO-LUMO gap ofExpand
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Solvent-Free Condensation of Pyrrole and Pentafluorobenzaldehyde: A Novel Synthetic Pathway to Corrole and Oligopyrromethenes
The solvent-free condensation of pyrrole and pentafluorobenzaldehyde (and to a lesser extent other electron-poor aldehydes as well) leads to a variety of products, of which three have been isolatedExpand
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Reduction of cobalt and iron corroles and catalyzed reduction of CO2
The role of cobalt and iron corroles in catalytic CO2 reduction has been studied. Chemical, electrochemical, and photochemical reductions of the stable metal corroles Ph3PCoIII(tpfc) (tpfc =Expand
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Iron(III) and iron(IV) corroles: synthesis, spectroscopy, structures, and no indications for corrole radicals.
A delicate control of reaction conditions allows the isolation of several distinctively different iron complexes of tris(pentafluorophenyl)- and tris(2,6-dichlorophenyl)corrole. As long asExpand
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Iron(IV) corroles are potent catalysts for aziridination of olefins by Chloramine-T
Iron(III) corroles were found to be more selective catalysts than analogous porphyrins for the aziridination of olefins by PhINTs, and, most important, the iron(IV) corrole 1 displays the uniqueExpand
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