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- Publications
- Influence
Synthesis and Mechanism of Formation of Novel NHC−NAC Bis-Carbene Complexes of Gold(I)
- L. Canovese, F. Visentin, C. Levi, V. Bertolasi
- Chemistry
- 19 January 2011
Novel [Au(NHC)(DIC)]BF4 complexes (NHC = SIMes, IMes, SIPr, IPr; DIC = 2,6-dimethylphenyl isocyanide) were synthesized and characterized. These substrates react with secondary amines at room… Expand
Reactivity of sulfoxides toward the tetrachloroplatinate(II) anion
- G. Annibale, L. Cattalini, L. Canovese, G. Michelon, G. Marangoni, M. L. Tobe
- Chemistry
- 28 June 1983
Reversible addition of protic molecules to co-ordinated di-2-pyridyl ketone in palladium(II), platinum(II), and gold(III) complexes. X-Ray crystal structures of…
- G. Annibale, L. Canovese, +4 authors A. Tiripicchio
- Chemistry
- 1981
Palladium(II), platinum(II), and gold(III) species react with di-2-pyridyl ketone (dpk) to give complexes in which one or two ligand molecules in the original keto- or in a newly formed diolic form… Expand
CIS EFFECT OF DIMETHYL SULFIDE AND THE LEAVING GROUP EFFECT IN REACTIONS OF THE CATIONIC COMPLEX CHLORO(DIMETHYL SULFIDE)(1,2-DIAMINOETHANE)PLATINUM(II) CHLORIDE
- M. Bonivento, L. Canovese, L. Cattalini, G. Marangoni, G. Michelon, M. L. Tobe
- Chemistry
- 9 February 1982
Kinetics of the displacement of cyclobutane-1,1-dicarboxylate from diammine(cyclobutane-1,1-dicarboxylato)platinum(II) in aqueous solution
- L. Canovese, L. Cattalini, G. Chessa, M. L. Tobe
- Chemistry
- 1988
The displacement of 1,1-cyclobutanedicarboxylate (cbdca2–) from [Pt(NH3)2(cbdca)] has been studied in aqueous solution. In the presence of acid the process resembles the successive displacement of… Expand
Palladium(0)-Catalyzed Cis−Trans Alkene Isomerizations
- L. Canovese, C. Santo, F. Visentin
- Chemistry
- 17 June 2008
The cis−trans isomerization of some olefins bearing strong electron-withdrawing substituents (dmma and E-tse) is catalyzed by their mere coordination to a suitable Pd(0) fragment without any external… Expand
Insertion of Isocyanides across the Pd−C Bond in Alkyl or Aryl Palladium(II) Complexes Bearing Mixed Nitrogen−Sulfur and Nitrogen−Phosphorus Ancillary Ligands. The Mechanism of Reaction
- L. Canovese, F. Visentin, C. Santo, C. Levi, A. Dolmella
- Chemistry
- 6 October 2007
An exhaustive study dealing with the kinetic and mechanistic behavior of alkyl- and arylpalladium complexes bearing pyridyl−thioethers (NS−R) and quinoline−phosphines (NP) as ancillary ligands when… Expand
The appearance of a stable intermediate in some substitution reactions of (1,5-diamino-3-azapentane)pyridinepalladium(II) perchlorate
- L. Canovese, L. Cattalini, P. Uguagliati, M. L. Tobe
- Chemistry
- 1990
The kinetics and equilibria of the reversible displacement of pyridine (py) from [Pd(dien)(py)]2+(dien = 1,5-diamino-3-azapentane) in aqueous solution have been studied. In acidic solution the… Expand
Migratory Insertion of Allyl Groups across the Pd−C Bond in Palladium(II) Isocyanide Complexes. The Fundamental Interplay between Temperature and Allyl Hapticity
- L. Canovese, F. Visentin, C. Santo, C. Levi
- Chemistry
- 6 November 2009
The 2,6-dimethylphenyl- and tert-butylisocyanides (DIC and TIC, respectively) react in chlorinated solvents with the allyl dimers [Pd(μ-Cl)(η3-C3H3Me2)]2 and [Pd(μ-Cl)(η3-C3H5)]2, giving the… Expand
Synthesis of new allyl palladium complexes bearing purine-based NHC ligands with antiproliferative and proapoptotic activities on human ovarian cancer cell lines.
- T. Scattolin, I. Caligiuri, +6 authors F. Visentin
- Chemistry, Medicine
- Dalton transactions
- 2 October 2018
A series of new palladium allyl complexes bearing purine-based carbenes derived from caffeine, theophylline and theobromine have been prepared and characterized by NMR spectroscopy, and elemental… Expand