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A novel radical approach for the direct conversion of RSO(2)X into RCOX in a single step is devised; the present approach is very simple, highly efficient, and minimizes formation of by-product.
A simple radical approach based on tin-free radical carbonylation is devised for the direct conversion of alkylthiosulfonates, alkylsulfonyl cyanides, and alkylsulfonyl oxime ethers into the corresponding alkyl thiol esters, acyl cyanides, and acylated oxime ethers in a single step. The present approach is very simple, highly efficient, and minimizes the… (More)