Krzysztof Slowinski

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Formation, structure, and properties of alkanethiolate monolayers on micrometrically driven hanging mercury drop electrodes were investigated electrochemically. Alkanethiols with the chain length from C 8 to C 18 were shown to form densely packed (ca. 20.3 Å 2 /molecule for C 12 SH), perpendicularly oriented monolayers on mercury in a process involving two(More)
Electron tunneling experiments involving Hg-Hg junctions incorporating two alkanethiolate monolayers are described. Formation of a symmetric junction (Hg-SC n-C n S-Hg) is accomplished by bringing in contact two small (3 × 10-3 cm 2) mercury drop electrodes in a 5-20% (v/v) hexadecane solution of an alkanethiol. Formation of asymmetric junctions (Hg-SC n-C(More)
The electrical conductance of ds-DNA duplexes containing 8-14 base pairs modified at both ends with a -(CH(2))(6)-SH linker was measured in a buffered aqueous solution using electrochemically controlled distance tunneling spectroscopy. The tunneling experiment with self-complementary 5'-(GC)(n)()-3'-(CH(2))(6)-SH (n = 4-7) duplexes attached covalently to a(More)
The rates of electron tunneling through monolayers and bilayers of alkanethiols self-assembled in a potentiostatically controlled Hg-Hg junction are reported. An alkanethiolate monolayer is formed in situ on one or both Hg drops via oxidative adsorption at the controlled potential. Subsequently, the Hg drops are brought into contact using micromanipulators.(More)
Scanning electrochemical microscopy (SECM) is used to probe long-range charge transport (CT) through DNA monolayers containing the redox-active Nile Blue (NB) intercalator covalently affixed at a specific location in the DNA film. At substrate potentials negative of the formal potential of covalently attached NB, the electrocatalytic reduction of(More)