Keshavamurthy Ramamurthy

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The title complex, [Zn(CH(5)N(3)S)(2)(C(2)H(6)OS)](C(6)H(2)N(3)O(7))(2)·C(2)H(6)OS·H(2)O, is composed of a [Zn(thio-semi-carbazide)(2)(DMSO)](2+) cation (where DMSO is dimethyl sulfoxide), and two picrate anions. In the asymmetric unit, there is also a solvent mol-ecule of DMSO and a water mol-ecule of crystallization. In the cation, the Zn(II) atom is(More)
In the cation of the title compound, [Cd(CH(5)N(3)S)(2)(C(2)H(6)OS)(2)](C(6)H(2)N(3)O(7))(2)·2H(2)O, the Cd(II) atom is located on an inversion center. It is hexa-coordinated in an octahedral fashion by two thio-semicarbazide mol-ecules, which coordinate in a bidentate manner via the S and N atoms, and to the O atom of two dimethyl sufoxide (DMSO)(More)
In the title compound, [CdI(2){(C(6)H(5))(3)PO}(2)], the Cd(II) atom is ligated by two I atoms and two O atoms from two triphenyl-phosphine oxide ligands in a disorted tetra-hedral arrangement. While the O-Cd-I angles vary from 106.67 (7) to 111.23 (7)°, the O-Cd-O angle is 88.60 (10)° and the I-Cd-I angle angle is 125.47 (2)°. The crystal structure is(More)
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