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Silica- and alumina-supported nickel phosphide (Nix Py ) catalysts have been prepared, characterized by bulk and surface sensitive techniques, and evaluated for the hydrodesulfurization (HDS) of… (More)
Abstract Silica-supported cobalt phosphide (Co x P y /SiO 2 ) catalysts, prepared from precursors having P/Co molar ratios in the range 0.50–2.0, were characterized and evaluated for thiophene… (More)
Pyridine adsorption on NiAl(100) and ultrathin films of γ-Al 2 O 3 was studied using high-resolution electron energy loss spectroscopy (HREELS). Pyridine adsorbs on NiAl(100) with its molecular axis… (More)
Ultrathin films of γ-Al 2 O 3 grown on NiAl(001) were studied using high-resolution electron energy loss spectroscopy (HREELS), Auger electron spectroscopy (AES), and low-energy electron diffraction… (More)
Abstract The interactions of benzene, toluene, acetonitrile, pyrazine, and pyridine with hydroxylated ultrathin films of γ -Al 2 O 3 were investigated using vibrational spectroscopy (high-resolution… (More)
- Greg Parks, Melissa L. Pease, +5 authors José A Rodriguez
- 2007
Unsupported and silica-supported amorphous metal-boron materials (Ni-B, Mo-O-B, and Ni-Mo-O-B) were prepared by NaBH4 reduction of aqueous or impregnated metal salts. The resulting materials were… (More)
The adsorption of CO on hydrated H2-, O2-, H2S-, and He-pretreated 5 wt % Ru/Al2O3 was investigated using attenuated total reflection IR spectroscopy (ATR-FTIR) to determine how the oxidation state… (More)
The adsorption of CO on hydrated 5 wt % Ru/Al2O3 produced νCO absorbance features at ∼2048, 1992, and 1924 cm-1 that are red-shifted by 50−116 cm-1 from those seen in the absence of water (2020−2040,… (More)
- Thomas A Shell, Jessica Elspeth Glass, Megan A. Mackey, Kathryn A. Layman, Debra L. Mohler
- Inorganic chemistry
- 2007
The complexes CpFe(CO)(2)Ph and [CpFe(CO)(2)](2) cleave DNA in the presence of H2O2 or organic peroxides to give products resulting from the formal hydrolysis of the phosphodiester groups.