Karen K Gleason

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The present study demonstrates the creation of a stable, superhydrophobic surface using the nanoscale roughness inherent in a vertically aligned carbon nanotube forest together with a thin, conformal hydrophobic poly(tetrafluoroethylene) (PTFE) coating on the surface of the nanotubes. Superhydrophobicity is achieved down to the microscopic level where(More)
A novel high-strength nano-adhesive is demonstrated for fabricating nano- and microfluidic devices. While the traditional plasma sealing methods are specific for sealing glass to poly(dimethylsiloxane) (PDMS), the new method is compatible with a wide variety of polymeric and inorganic materials, including flexible substrates. Additionally, the traditional(More)
Flow lithography has become a powerful particle synthesis technique. Currently, flow lithography relies on the use of polydimethylsiloxane microchannels, because the process requires local inhibition of polymerization, near channel interfaces, via oxygen permeation. The dependence on polydimethylsiloxane devices greatly limits the range of precursor(More)
Smooth, durable, ultrathin antifouling layers are deposited onto commercial reverse osmosis membranes without damaging them and they exhibit a fouling reduction. A new synergistic approach to antifouling, by coupling surface modification and drinking-water-level chlorination is enabled by the films' unique resistance against chlorine degradation. This(More)
Blockage of pipelines by formation and accumulation of clathrate hydrates of natural gases (also called gas hydrates) can compromise project safety and economics in oil and gas operations, particularly at high pressures and low temperatures such as those found in subsea or arctic environments. Cyclopentane (CyC5) hydrate has attracted interest as a model(More)
LIBRARIES The Author hereby grants to MIT permission to reproduce and to distribute publicly paper and electronic copies of this thesis document in whole or in part in any medium now known or hereafter created. Abstract Electrospinning is a convenient method to produce nanofibers with controlled diameters on the order of tens to hundreds of nanometers. The(More)
The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Abstract The formation of patterned surfaces is a common tool to engineer materials. The capability to design and reproduce detailed features is a key factor to fulfill requirements for functional surfaces. Generation of wrinkles via(More)
The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Abstract Preferred crystallographic orientation (texture) in thin films frequently has a strong effect on the properties of the materials and it is important for stable surface properties. Organized molecular films of(More)
Ubiquitous, low power consumption and high bandwidth density communication will require passive athermal optical filters for WDM transceivers in Si-CMOS architecture. Two silicon-polymer composite structures, deposited using initiated chemical vapor deposition (iCVD), poly(perfluorodecyl acrylate) (pPFDA) and poly(perfluorodecyl acrylate-co-divinyl benzene)(More)
simple method to fabricate a multifunctional patterned platform on the nanometer scale is demonstrated. The platform contains two reactive functional groups on the surface: one is an acetylene group which can be functionalized via click chemistry, and the other is an amine group which can also be functionalized by classic carbodiimide chemistry with(More)
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