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The photocatalytic water reduction reaction on CdS nanorods was studied as function of Pt cluster size. Maximum H2 production is found for Pt46. This effect is attributed to the size dependent electronic properties (e.g., LUMO) of the clusters with respect to the band edges of the semiconductor. This observation may be applicable for the study and(More)
Highly active catalysts for the oxygen evolution reaction (OER) are required for the development of photoelectrochemical devices that generate hydrogen efficiently from water using solar energy. Here, we identify the origin of a 500-fold OER activity enhancement that can be achieved with mixed (Ni,Fe)oxyhydroxides (Ni(1-x)Fe(x)OOH) over their pure Ni and Fe(More)
We introduce size-selected subnanometer cluster catalysts deposited on thin films of colloidal semiconductor nanocrystals as a novel platform to obtain atomic scale insight into photocatalytic generation of solar fuels. Using Pt-cluster-decorated CdS nanorod films for photocatalytic hydrogen generation as an example, we determine the minimum amount of(More)
Photocatalytic overall water splitting requires co-catalysts that efficiently promote the generation of H2 but do not catalyze its reverse oxidation. We demonstrate that CO chemisorbed on metal co-catalysts (Rh, Pt, Pd) suppresses the back reaction while maintaining the rate of H2 evolution. On Rh/GaN:ZnO, the highest H2 production rates were obtained with(More)
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