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- Publications
- Influence
Simple and selective method for RCHO → (E)-RCH=CHX conversion by means of a CHX3-CrCl2 system
- K. Takai, K. Nitta, K. Utimoto
- Chemistry
- 1 November 1986
Insertion of polar and nonpolar unsaturated molecules into carbon-rhenium bonds generated by C-H bond activation: synthesis of phthalimidine and indene derivatives.
- Y. Kuninobu, Y. Tokunaga, A. Kawata, K. Takai
- Chemistry, Medicine
- Journal of the American Chemical Society
- 11 January 2006
A rhenium complex, [ReBr(CO)(3)(thf)](2), catalyzes the reaction of an aromatic aldimine with an isocyanate and an acetylene to give a phthalimidine and an indene derivative in a quantitative yield,… Expand
Rhenium-catalyzed formation of indene frameworks via C-H bond activation: [3+2] annulation of aromatic aldimines and acetylenes.
- Y. Kuninobu, A. Kawata, K. Takai
- Chemistry, Medicine
- Journal of the American Chemical Society
- 8 September 2005
A rhenium complex, [ReBr(CO)3(thf)]2, catalyzes the reaction of an aromatic aldimine with an acetylene to give an indene derivative in a quantitative yield. The reaction proceeds via C-H bond… Expand
Palladium-catalyzed ortho-selective C-H borylation of 2-phenylpyridine and its derivatives at room temperature.
- Y. Kuninobu, T. Iwanaga, T. Omura, K. Takai
- Chemistry, Medicine
- Angewandte Chemie
- 15 April 2013
Direct C H bond transformations have received much attention as ideal and highly efficient methods for the synthesis of useful organic compounds. However, several difficulties remain, in particular… Expand
Dramatic Rate Acceleration by a Diphenyl-2-pyridylphosphine Ligand in the Hydration of Nitriles Catalyzed by Ru(acac)2 Complexes
- T. Oshiki, H. Yamashita, K. Sawada, M. Utsunomiya, Takahashi Kazunari, K. Takai
- Chemistry
- 18 November 2005
New ruthenium(II) complexes having acac (=acetylacetonato) and diphenyl-2-pyridylphosphine as ligands proved to be excellent catalysts for hydration of nitriles to amides under neutral conditions.… Expand
Nanoelectromechanical nonvolatile memory device incorporating nanocrystalline Si dots
- Yoshishige Tsuchiya, K. Takai, +5 authors T. Shimada
- Materials Science
- 3 November 2006
A nanoelectromechanical device incorporating the nanocrystalline silicon (nc-Si) dots is proposed for use as a high-speed and nonvolatile memory. The nc-Si dots are embedded as charge storage in a… Expand
Reactions of Alkenylchromium Reagents Prepared from Alkenyl Trifluoromethanesulfonates (Triflates) with Chromium(II) Chloride Under Nickel Catalysis.
- K. Takai, M. Tagashira, T. Kuroda, K. Oshima, K. Utimoto, H. Nozaki
- Chemistry
- 3 February 1987
Rhenium-Catalyzed Construction of Polycyclic Hydrocarbon Frameworks by a Unique Cyclization of 1,n-Diynes Initiated by 1,1-Difunctionalization with Carbon Nucleophiles.
- Masahito Murai, Erika Uemura, Shunsuke Hori, K. Takai
- Chemistry, Medicine
- Angewandte Chemie
- 15 May 2017
A regioselective cyclization of 1,n-diynes under rhenium catalysis was developed on the basis of a rare type of 1,1-difunctionalization of terminal alkynes with carbon nucleophiles, followed by… Expand