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Catalytic hydrogenation of carbon dioxide using Ir(III)-pincer complexes.
Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. PotassiumExpand
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Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion
Nucleophilic, anionic boryl compounds are long-sought but elusive species. We report that reductive cleavage of the boron-bromine bond inExpand
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Copolymerization of Propylene and Polar Monomers Using Pd/IzQO Catalysts.
  • R. Nakano, K. Nozaki
  • Chemistry, Medicine
  • Journal of the American Chemical Society
  • 19 August 2015
Palladium catalysts bearing imidazo[1,5-a]quinolin-9-olate-1-ylidene (IzQO) ligands polymerize α-olefins while incorporating polar monomers. The steric environment provided by N-heterocyclic-carbeneExpand
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Facile estimation of catalytic activity and selectivities in copolymerization of propylene oxide with carbon dioxide mediated by metal complexes with planar tetradentate ligand.
Mechanistic studies were conducted to estimate (1) catalytic activity for PPC, (2) PPC/CPC selectivity, and (3) PPC/PPO selectivity for the metal-catalyzed copolymerization of propylene oxide withExpand
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Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex
The PNP-ligated iridium(III) trihydride complex 1 exhibited the highest catalytic activity for hydrogenation of carbon dioxide in aqueous KOH. The catalytic hydrogenation can be tuned to be aExpand
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Highly Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of New Chiral Phosphine−Phosphite Ligands
A new chiral phosphine−phosphite ligand, (R)-2-(diphenylphosphino)-1,1‘-binaphthalen-2‘-yl (S)-1,1‘-binaphthalene-2,2‘-diyl phosphite [(R,S)-BINAPHOS, (R,S)-2a], was synthesized. Its Rh(I) complexExpand
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Copper-Catalyzed Hydroboration of Carbon Dioxide
A copper/N-heterocyclic carbene catalyzed hydroboration of carbon dioxide has been developed to give a formic acid derivative selectively under mild conditions. Investigations directed towardExpand
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Tetravalent metal complexes as a new family of catalysts for copolymerization of epoxides with carbon dioxide.
New tetravalent metal complexes with a trianionic [ONNO]-tetradentate ligand and an ancillary chloride ligand were synthesized as catalysts for the copolymerization of epoxides with carbon dioxideExpand
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