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Kinetics and Mechanism of the Decomposition of Chlorous Acid
The kinetics of decomposition of aqueous chlorous acid has been reinvestigated at pH 0.7−1.9, ionic strength 1.0 M (HSO4-/SO42-), and temperature 25.0 ± 0.1 °C. Optical absorbances were collected in
Isolation, properties and structural studies on a compound from tunicate blood cells that may be involved in vanadium accumulation.
A novel compound, for which the trivial name tunichrome is proposed, was isolated from the vanadium-rich blood cells of the tunicate Ascidia niga, and it is suggested that the presence of Tunichrome may be linked to vanadium accumulation by the blood cells.
Mechanistic study of oscillations and bistability in the Cu(II)-catalyzed reaction between H2O2 and KSCN
The CuS04-catalyzed reaction of hydrogen peroxide with thiocyanate ion is the first example of a homogeneous, liquid phase, halogen-free system that oscillates under batch conditions. A detailed
A systematically designed homogeneous oscillating reaction: the arsenite-iodate-chlorite system
Journal of the American Chemical Society is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 A systematically designed homogeneous oscillating reaction:
Kinetics and mechanism of the oxidation of thiourea by bromate in acidic solution
The reaction between bromate and thiourea has been studied in acidic medium. The stoichiometry of the reaction in excess thiourea is 4BrO 3 - +3SC(NH 2 ) 2 +3H 2 O→3SO 4 2- +3OC(NH 2 ) 2 +4Br - +6H +