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One-Pot Synthesis of Cyclopropane-Fused Cyclic Amidines: An Oxidative Carbanion Cyclization.
A novel and efficient one-pot method for the synthesis of cyclopropane-fused bicyclic amidines on the basis of a CuBr2 -mediated oxidative cyclization of carbanions that provides straightforward access to biologically active and pharmaceutically important 3-azabicyclo[n.1.0]alkane frameworks under mild conditions.
Transition Metal Free Synthesis of Heterobiaryls Through 1,2-Migration of Boronate Complex.
The synthesis of a diverse range of heterobiaryl has been achieved via a transition metal free sp 2 -sp 2 cross coupling strategy using lithiated heterocycle, aryl or heteroaryl boronic ester and an
Transition metal-free synthesis of alkyl pinacol boronates.
This work analyzed the growing resource of literature related to the transition metal-free synthesis of alkyl pinacol boronic esters based on the differences in their reaction mechanisms to derive conclusions about the synthesis of C-B bonds in the absence of transition metals.
Functionalization of Heterocycles Through 1,2-Metallate Rearrangement of Boron Ate Complex.
This minireview highlights the methods known till date for the synthesis of heteroaryls using 1,2-migration of boronate complex in a chronological manner.
Silver oxide mediated novel SET oxidative cyclization: stereoselective synthesis of 3-azabicyclo[n.1.0]alkanes.
For the first time, silver oxide catalyzed SET-oxidative cyclization of an α-amidinoester tethered with an alkene, leading to a novel cyclopropane-fused cyclic amidine, allowing easy access to the pharmaceutically important 3-azabicyclo[n.1.0]alkane framework.
Recent developments in asymmetric synthesis and functionalization of symmetrical and unsymmetrical gem-diborylalkanes
Gem-diborylalkanes are an important class of organoboron compounds as they function as a key building block in organic synthesis. In the last decade, there has been a growing interest in...
Synthesis and reactivity of alkynyl boron compounds.
In this review, the advancement of research on alkynyl boron compounds is summarized, highlighting their importance in the synthesis of valuable compounds.