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One-Pot Synthesis of Cyclopropane-Fused Cyclic Amidines: An Oxidative Carbanion Cyclization.
A novel and efficient one-pot method for the synthesis of cyclopropane-fused bicyclic amidines on the basis of a CuBr2 -mediated oxidative cyclization of carbanions that provides straightforward access to biologically active and pharmaceutically important 3-azabicyclo[n.1.0]alkane frameworks under mild conditions.
Transition Metal Free Synthesis of Heterobiaryls Through 1,2-Migration of Boronate Complex.
The synthesis of a diverse range of heterobiaryl has been achieved via a transition metal free sp 2 -sp 2 cross coupling strategy using lithiated heterocycle, aryl or heteroaryl boronic ester and an…
Transition metal-free synthesis of alkyl pinacol boronates.
This work analyzed the growing resource of literature related to the transition metal-free synthesis of alkyl pinacol boronic esters based on the differences in their reaction mechanisms to derive conclusions about the synthesis of C-B bonds in the absence of transition metals.
Functionalization of Heterocycles Through 1,2-Metallate Rearrangement of Boron Ate Complex.
This minireview highlights the methods known till date for the synthesis of heteroaryls using 1,2-migration of boronate complex in a chronological manner.
A new avenue for the preparation of organoboron compounds via nickel catalysis
Synthesis and Reactivity of Allenylboron Compounds
Silver oxide mediated novel SET oxidative cyclization: stereoselective synthesis of 3-azabicyclo[n.1.0]alkanes.
For the first time, silver oxide catalyzed SET-oxidative cyclization of an α-amidinoester tethered with an alkene, leading to a novel cyclopropane-fused cyclic amidine, allowing easy access to the pharmaceutically important 3-azabicyclo[n.1.0]alkane framework.
Recent developments in asymmetric synthesis and functionalization of symmetrical and unsymmetrical gem-diborylalkanes
Gem-diborylalkanes are an important class of organoboron compounds as they function as a key building block in organic synthesis. In the last decade, there has been a growing interest in...
Frontispiece: Functionalization of Heterocycles through 1,2‐Metallate Rearrangement of Boronate Complexes
Synthesis and reactivity of alkynyl boron compounds.
- Soumilee Nandy, Swagata Paul, K. K. Das, Parveen Kumar, Debraj Ghorai, S. Panda
- ChemistryOrganic & biomolecular chemistry
- 7 July 2021
In this review, the advancement of research on alkynyl boron compounds is summarized, highlighting their importance in the synthesis of valuable compounds.