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Recognition of ionic guests by ionic beta-cyclodextrin derivatives.
Inclusion compounds of cationic, anionic, and neutral p-substituted derivatives of tert-butylbenzene complexed in beta-cyclodextrin and its ionic 6-mono and 6-hepta derivatives were systematically
An iron polyolate complex as a precursor for the controlled synthesis of monodispersed iron oxide colloids
A simple procedure that applies a hexanuclear iron-polyolate complex as an iron oxide precursor has been developed for the synthesis of colloidal iron oxide particles. The hydrolysis of this complex
Complex Formation of ICL670 and Related Ligands with FeIII and FeII
Complex formation of 4-[3,5-bis(2-hydroxyphenyl)-1,2,4-triazol-1-yl]benzoic acid (ICL670, H3Lx), 4-[3,5-bis(2-hydroxyphenyl)-1,2,4-triazol-1-yl]benzosulfonic acid (H3Ly), and
HYDROLYSIS OF THE ORGANOMETALLIC AQUA ION FAC-TRIAQUATRICARBONYLRHENIUM(I). MECHANISM, PKA, AND FORMATION CONSTANTS OF THE POLYNUCLEAR HYDROLYSIS PROD UCTS
Hydrolytic pathways of the organometallic aqua ion [Re(CO)3(H2O)3]+ (2) in aqueous media were investigated by means of potentiometric titration experiments. The aqua complex 2 was obtained
Kinetics and mechanisms of the oxidation of myoglobin by Fe(III) and Cu(II) complexes.
TLDR
Two distinct mechanisms by which sperm whale myoglobin reduces complexes of Fe(III) and Cu(II) and, in turn, is oxidized to metmyoglobin have been characterized and a scheme for the participation of either or both of these mechanisms in reduction reactions of heme proteins is proposed.
4-3,5-BIS(2-HYDROXYPHENYL)-1,2,4-TRIAZOL-1-YL-BENZOIC ACID : A NOVEL EFFICIENT AND SELECTIVE IRON(III) COMPLEXING AGENT
An exceptionally stable 1:2 complex [FeL2]3− is formed from the ligand H3L and FeIII. In contrast, the affinity of this ligand for other biometals is relatively small. These properties make H3L a
Interaction of copper(II) with N-(2-hydroxyethyl)piperazine-N'-ethanesulfonic acid (HEPES)
Interaction consistant en une complexation avec Cu (II) et une reaction avec les ions metalliques. La reaction de Cu (II) est du 1er ordre par rapport a HEP E et du 2eme ordre par rapport a Cu (II)
A rigid, cyclohexane-based polyamino-polyalcohol as a versatile building block for tailored chelating agents
Selective, tailored chelators are of importance in medicine for the treatment of metal intoxication, or to stabilise metal cations in diagnostic radiopharmaceuticals and paramagnetic contrast agents.
Trinuclear Lanthanoid Complexes of 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol with a Unique, Sandwich-Type Cage Structure(1).
TLDR
The two trinuclear complexes exhibited a unique, sandwich-type cage structure, where the two triply deprotonated taci ligands encapsulate an equilateral triangle of the three metal centers.
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