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Synthesis, spectral, and single-crystal X-ray structural analysis of meso-aryl triphyrin(2.1.1) featuring three pyrrole rings and four meso-aryl rings are described. The title compound represents the first example of a ring-contractedmeso-aryl β-unsubstituted free-base triphyrin containing only pyrrole rings reported to date and generates 2-D supramolecular(More)
The syntheses and spectral and structural characterization of hitherto unknown p-benzene incorporated normal, expanded, strapped and N-confused calixbenzophyrins are achieved; altogether five new macrocycles from a single starting material are reported. The binding studies of the strapped macrocycle revealed that the molecule is selective towards Fe(III)(More)
meso-Tetraarylporphycenes, structural isomers of meso-tetraarylporphyrins, were synthesized by the acid-catalyzed oxidative coupling reaction for the first time which is an alternative synthetic methodology to the traditional McMurry coupling reaction. The structure of the macrocycle and Ni(II) complex are characterized by single-crystal X-ray diffraction(More)
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