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Characterizing Pressure-Induced Uranium C=H Agostic Bonds**

• Polly L Arnold, Alessandro Prescimone, Joy H Farnaby, Stephen M. Mansell, Simon Parsons, Nikolas Kaltsoyannis
• Angewandte Chemie
• 2015

The diuranium(III) compound [UN''2]2(μ-η(6):η(6)-C6H6) (N''=N(SiMe3)2) has been studied using variable, high-pressure single-crystal X-ray crystallography, and density functional theory . In this… (More)

Synthesis and catalytic activity of iron complexes with bidentate NHC ligands.

• J. C. K. Wu, Wei Dai, +6 authors Michael K. Takase
• Dalton transactions
• 2013

A family of well-defined Fe(II) complexes of the type {BnN(N-CH2(CH2)n-N'-tert-butyl-imidazole-2-ylidene)2}FeCl2 (Bn = benzyl; n = 1 (1) or 2 (2)),… (More)

Isolation of (CO)1- and (CO2)1- radical complexes of rare earths via Ln(NR2)3/K reduction and [K2(18-crown-6)2]2+ oligomerization.

• Ming Fang, Joy H Farnaby, Joseph W Ziller, Jefferson E Bates, Filipp Furche, William J Evans
• Journal of the American Chemical Society
• 2012

Deep-blue solutions of Y(2+) formed from Y(NR(2))(3) (R = SiMe(3)) and excess potassium in the presence of 18-crown-6 at -45 °C under vacuum in diethyl ether react with CO at -78 °C to form colorless… (More)

Organometallic neptunium(III) complexes.

• Michał S. Dutkiewicz, Joy H Farnaby, +8 authors Polly L Arnold
• Nature chemistry
• 2016

Studies of transuranic organometallic complexes provide a particularly valuable insight into covalent contributions to the metal-ligand bonding, in which the subtle differences between the… (More)

Group 4 metal compounds incorporating the amide ligand, [N(SiMe2{C6H4-2-OMe})2](-).

• Lloyd T J Evans, Joy H Farnaby, Martyn P Coles, F Geoffrey N Cloke, Peter Hitchcock
• Dalton transactions
• 2015

The anisole-substituted silyl-amide anion, [N(SiMe2{C6H4-2-OMe})2](-) (L), has been used as a pincer-type ligand in coordination chemistry. X-ray diffraction data for the lithium salt shows a… (More)

Expanding yttrium bis(trimethylsilylamide) chemistry through the reaction chemistry of (N2)2-, (N2)3-, and (NO)2- complexes.

• Joy H Farnaby, Ming Fang, Joseph W Ziller, William J Evans
• Inorganic chemistry
• 2012

The reaction chemistry of the side-on bound (N(2))(2-), (N(2))(3-), and (NO)(2-) complexes of the [(R(2)N)(2)Y](+) cation (R = SiMe(3)), namely, [(R(2)N)(2)(THF)Y](2)(μ-η(2):η(2)-N(2)), 1,… (More)

New chemistry from an old reagent: mono- and dinuclear macrocyclic uranium(III) complexes from [U(BH4)3(THF)2].

• Polly L Arnold, Charlotte J. Stevens, Joy H Farnaby, Michael G Gardiner, Gary S Nichol, Jason B Love
• Journal of the American Chemical Society
• 2014

A new robust and high-yielding synthesis of the valuable U(III) synthon [U(BH4)3(THF)2] is reported. Reactivity in ligand exchange reactions is found to contrast significantly to that of uranium… (More)

Varying the Lewis base coordination of the Y2N2 core in the reduced dinitrogen complexes {[(Me3Si)2N]2(L)Y}2(μ-η2:η2-N2) (L = benzonitrile, pyridines, triphenylphosphine oxide, and trimethylamine…

• Jordan F Corbey, Joy H Farnaby, Jefferson E Bates, Joseph W Ziller, Filipp Furche, William J Evans
• Inorganic chemistry
• 2012

The effect of the neutral donor ligand, L, on the Ln(2)N(2) core in the (N═N)(2-) complexes, [A(2)(L)Ln](2)(μ-η(2):η(2)-N(2)) (Ln = Sc, Y, lanthanide; A = monoanion; L = neutral ligand), is unknown… (More)

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