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An exceptionally fast homogeneous carbon-free cobalt-based water oxidation catalyst.

• Hongjin Lv, Jie Song, +8 authors Craig L Hill
• Journal of the American Chemical Society
• 2014

An all-inorganic, oxidatively and thermally stable, homogeneous water oxidation catalyst based on redox-active (vanadate(V)-centered) polyoxometalate ligands, Na10[Co4(H2O)2(VW9O34)2]·35H2O… (More)

Differentiating homogeneous and heterogeneous water oxidation catalysis: confirmation that [Co4(H2O)2(α-PW9O34)2]10- is a molecular water oxidation catalyst.

• James W Vickers, Hongjin Lv, +5 authors Craig L Hill
• Journal of the American Chemical Society
• 2013

Distinguishing between homogeneous and heterogeneous catalysis is not straightforward. In the case of the water oxidation catalyst (WOC) [Co4(H2O)2(PW9O34)2](10-) (Co4POM), initial reports of an… (More)

Complexation of metal carbonyl units with [α-PW11O39]7- and [α2-P2W17O61]10-: insights into the chiral "twisted-sandwich" dimeric structures.

• Chongchao Zhao, Elliot N Glass, +4 authors Craig L Hill
• Dalton transactions
• 2014

Several polyoxometalate-supported metal carbonyl complexes, K7Na3P2W23O80{Re(CO)3}2·38H2O (1), (C3H10N)8Na2P2W23O80{Re(CO)3}2·10H2O (1a) and (C3H10N)6KNa3P2W23O80{Mn(CO)3}2·7H2O (2), have been… (More)

All-inorganic networks and tetramer based on tin(II)-containing polyoxometalates: tuning structural and spectral properties with lone-pairs.

• Chongchao Zhao, Elliot N Glass, +5 authors Craig L Hill
• Journal of the American Chemical Society
• 2014

Two MOF-like but all-inorganic polyoxometalate-based networks, [Na7X2W18Sn9Cl5O68·(H2O)m]n (1, X = Si, m = 35; 2, X = Ge, m = 41), and the molecular tetramer… (More)

Collecting meaningful early-time kinetic data in homogeneous catalytic water oxidation with a sacrificial oxidant.

• James W Vickers, Jordan M Sumliner, Hongjin Lv, Mike Morris, Yurii V. Geletii, Craig L Hill
• Physical chemistry chemical physics : PCCP
• 2014

As the field of water oxidation catalysis grows, so does the sophistication of the associated experimental apparatuses. However, problems persist in studying some of the most basic aspects of… (More)

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