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- Publications
- Influence
Oxidative addition of arsenic halides to platinum(0).
- Jonas H. Muessig, Tom E. Stennett, U. Schmidt, Rian D. Dewhurst, L. Mailaender, H. Braunschweig
- Chemistry, Medicine
- Dalton transactions
- 12 March 2019
Reaction of AsCl3 with Pt(0) complexes [Pt(PCy3)2], [Pt(PCy3)(IMes)] and [Pt(IMes)2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) resulted in oxidative addition of As-Cl bonds at the Pt… Expand
Scope of the Thermal Ring-Expansion Reaction of Boroles with Organoazides.
- H. Braunschweig, M. A. Çelik, +9 authors Annika Ruppert
- Chemistry, Medicine
- Chemistry
- 12 June 2017
Electronic and steric factors have been investigated in the thermal ring expansion of boroles with organic azides, a reaction that provides access to highly arylated 1,2-azaborinines, BN analogues of… Expand
Engineering a Small HOMO-LUMO Gap and Intramolecular C-H Borylation by Diborene/Anthracene Orbital Intercalation.
- S. R. Wang, Merle Arrowsmith, +10 authors J. Zhang
- Chemistry, Medicine
- Angewandte Chemie
- 26 June 2017
The diborene 1 was synthesized by reduction of a mixture of 1,2-di-9-anthryl-1,2-dibromodiborane(4) (6) and trimethylphosphine with potassium graphite. The X-ray structure of 1 shows the two anthryl… Expand
Simple solution-phase syntheses of tetrahalodiboranes(4) and their labile dimethylsulfide adducts.
- Merle Arrowsmith, Julian Boehnke, +6 authors Jonas H. Muessig
- Medicine, Chemistry
- Chemical communications
- 20 July 2017
Convenient solution-phase syntheses of tetrahalodiboranes(4) B2F4, B2Cl4 and B2I4 are presented herein from common precursor B2Br4. In addition, the dimethylsulfide adducts B2Cl4(SMe2)2 and… Expand
Generierung einer kleinen HOMO‐LUMO‐Lücke und intramolekulare C‐H‐Borylierung durch Diboren‐Anthracen‐Orbitalinterkalation
- S. R. Wang, Merle Arrowsmith, +10 authors J. Zhang
- Chemistry
- 26 June 2017
Diboren 1 wurde durch Reduktion einer Mischung aus 1,2-Di-9-anthryl-1,2-dibromdiboran(4) (6) und Trimethylphosphan mit Kaliumgraphit dargestellt. Die Molekulstruktur von 1 zeigt, dass die… Expand
Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds.
- Jonas H. Muessig, Melanie Thaler, +5 authors H. Braunschweig
- Chemistry, Medicine
- Angewandte Chemie
- 22 March 2019
The lability of B=B, B-P, and B-halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes undergo cleavage of all six of their… Expand
Phosphanstabilisierte Diioddiborene: Isolierbare Diborene mit sechs labilen Bindungen
- Jonas H. Muessig, Melanie Thaler, +5 authors H. Braunschweig
- Chemistry
- 22 March 2019
Dynamic, Reversible Oxidative Addition of Highly Polar Bonds to a Transition Metal.
- R. Bertermann, Julian Boehnke, +7 authors A. Vargas
- Chemistry, Medicine
- Journal of the American Chemical Society
- 29 November 2016
The combination of Pt0 complexes and indium trihalides leads to compounds that form equilibria in solution between their In-X oxidative addition (OA) products (PtII indyl complexes) and their… Expand
Transition-Metal π-Ligation of a Tetrahalodiborane.
- H. Braunschweig, Rian D. Dewhurst, J. O. C. Jiménez-Halla, E. Matito, Jonas H. Muessig
- Chemistry, Medicine
- Angewandte Chemie
- 8 January 2018
The reaction of tetraiododiborane (B2 I4 ) with trans-[Pt(BI2 )I(PCy3 )2 ] gives rise to the diplatinum(II) complex [{(Cy3 P)(I2 B)Pt}2 (μ2 :η3 :η3 -B2 I4 )], which is supported by a bridging… Expand
Reactions of Digallanes with p- and d-Block Lewis Bases: Adducts, Bis(gallyl) Complexes, and Naked Ga+ as Ligand.
- J. Schuster, Jonas H. Muessig, Rian D. Dewhurst, H. Braunschweig
- Chemistry, Medicine
- Chemistry
- 5 July 2018
A range of double carbene adducts of digallanes(4) are prepared from an existing double digallane adduct, and their halides are subsequently exchanged, establishing the feasibility of both base and… Expand