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Two dibenzoxanthenium derivatives bearing a 3,4-diaminophenyl group, compounds 1a and 1b, have been prepared and evaluated as near-infrared probes for the detection of nitric oxide. Compound 1a gave a 3-fold emission enhancement towards nitric oxide at 681 nm, whereas compound 1b exhibited OFF-ON emission behavior towards nitric oxide, resulting in a(More)
Oxazinium derivatives have recently played an important role in bioanalysis attributing to the distinguished properties, thus a detailed study of the structure-property relationship is especially significant. Herein, pH-sensitive optical properties of Nile Blue (1a), N-monoalkyl-Nile Blue (1b) and Azure A (1c) have been carried out in extreme acid and base(More)
The combination of ditopic ligand 4-(8-hydroxyquinoline-5-azo)-benzensulfonic acid (H2QBS) with metal ions (M = Na(+), Pb(2+), Zn(2+), Mn(2+), Cd(2+)) leads to five different coordination polymers (CPs): [Na2(QBS)(H2O)2]n (1 , 3D framework), {[Pb(QBS)(DMSO)]·2((i)PrOH)}n (2·2(i)PrOH, 2D layer), {[Zn(QBS)(DMSO)]·2DMSO}n (3·2DMSO, 1D chain),(More)
A cyanobenzo[a]phenoxazine-based pH probe with pKa = 5.0 exhibits OFF-ON emission at 625-850 nm upon excitation at 600 nm in aqueous buffers. The in cellulo imaging experiments with HeLa cells indicate that the probe can serve as a lysosome-specific probe under red light excitation (633 nm) with near infrared emission (650-790 nm).
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