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Alkynyl-protected gold and gold-silver nanoclusters.
TLDR
It is demonstrated that alkynyls are very promising ligands in the control of the structures and properties of gold/silver nanoclusters.
Ligand effects in catalysis by atomically precise gold nanoclusters
TLDR
This work presents a clear demonstration that catalytic performance of gold nanoclusters can be modulated by the controlled construction of ligand spheres.
Chiroptical Activity Enhancement via Structural Control: The Chiral Synthesis and Reversible Interconversion of Two Intrinsically Chiral Gold Nanoclusters.
TLDR
This work demonstrates that the chiroptical activity of gold nanoclusters can be modulated by structural control through the introduction of second ligands.
C 20 - T carbon: a novel superhard sp (3) carbon allotrope with large cavities.
TLDR
Through first-principles calculations, a new superhard carbon allotrope is predicted, which possesses a cubic T symmetry with space group No.198(P213), which has an all-sp (3) hybridized bonding network with 20 atoms in its primitive unit cell.
A Route to Enantiopure ( O-Methyl)6-2,6-Helic[6]arenes: Synthesis of Hexabromo-Substituted 2,6-Helic[6]arene Derivatives and Their Suzuki-Miyaura Coupling Reactions.
TLDR
It was found that racemic and enantiopure ( O-methyl)6-2,6-helic[6]arene derivatives 5a-f with deepened cavities could be conveniently synthesized in 55-71% yield by Suzuki-Miyaura coupling reactions of 4 and arylboronic acids.
The df-d Dative Bonding in a Uranium-Cobalt Heterobimetallic Complex for Efficient Nitrogen Fixation.
TLDR
The study demonstrates the viability of metal → metal dative bonds, particularly the df-d one, for the reduction of N2 to NH3, and thus, this opens up a new avenue to the rational design of efficient catalyst for nitrogen fixation.
Microwave assisted synthesis of metal‐organic framework MIL‐101 nanocrystals as sorbent and pseudostationary phase in capillary electrophoresis for the separation of anthraquinones in environmental
TLDR
The CE method has been successfully applied to determine trace anthraquinones in environmental water samples and was optimized considering time, pH, buffer ionic strength, and nanoparticles concentration.
Ultrastable Matryoshka [Hf13] Nanocluster as a Luminescence Sensor for Concentrated Alkali and Acid.
TLDR
This work presents the first discrete neutral cluster, Hf13(μ4-O)8(OCH3)36 (1), which features extraordinary chemical stability with preserving crystalline state in both concentrated acid and alkali aqueous solution.
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