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An analysis of errors has been done with the Monte Carlo method for natural abundance 13C-NMR relaxation studies of a DNA duplex. Repeated measurements of the longitudinal relaxation time, T1, and the heteronuclear NOE were made at 90.6 MHz on the duplexed DNA pentanucleotide, [d(TCGCG)]2. The deviations averaged over all carbons were 13% for T1 and 9% for… (More)