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Abstract We propose a framework for embedding model predictive control for Systems-on-a-Chip applications. In order to allow the implementation of such a computationally expensive controller on chip,… (More)
El cedro rosado (Acrocarpus fraxinifolius Wight) es un arbol tropical apreciado por su madera densa, resistente y facil de trabajar. El objetivo de este proyecto fue evaluar el comportamiento del… (More)
A simple and stereoselective synthesis of secondary E-allylamines 1 and 20 from functionalized enamines derived from phosphine oxides 8, phosphonium salts 11 and phosphonates 12 is reported.… (More)
The presented lithium enolate-based methodology is suitable for access to propionate syn-aldol motifs with high levels of stereocontrol. The reactive lithium enolate species is generated by direct… (More)
The objective of this work is the implementation of a parameter identification option in the package DESIS. DESIS is a computational tool which allows the modeling and simulation of any non-linear… (More)
Reaction between a variety of bis(trimethylsilyl)methyl derivatives and carbonyl compounds under fluoride ion as catalyst is described. The reaction works especially well with nonenolizable carbonyl… (More)
α,γ-Disubstituted β-amino ketones were obtained by ring opening of 3,4- disubstituted N-Boc-β-lactams, promoted by Grignard and organocuprate reagents
A new one step synthesis of α,α-disubstituted α-amino acid N-carboxy anhydrides from α-hydroxy β-lactams and their coupling with α-aminoesters promoted by KCN is described.
Abstract A new camphor-derived imidazolidinone type auxiliary is described. Its acylated derivatives under Na enolate formation and treatment with primary halides give alkylated products in highly… (More)