Jessica Cid

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The addition of AlCl 3 to four-coordinate boranes of the general formula (C−N-chelate)BCl 2 results in halide abstraction and formation of three-coordinate borenium cations of the general formula [(C−N-chelate)BCl] +. The latter react with both arylstannanes and arylsilanes by boro-destannylation and-desilylation, respectively, to form arylated boranes.(More)
A combination of in situ IR spectroscopy (ReactIR) and DFT calculations have been used to understand what factors govern the selectivity in the addition of primary amines to α,β-unsaturated aldehydes and ketones, i.e., 1,2- versus 1,4-addition. It has been found that the 1,2-addition products (α,β-unsaturated imines following addition and elimination)(More)
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