Jeremy M Lenhardt

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Transition state structures are central to the rates and outcomes of chemical reactions, but their fleeting existence often leaves their properties to be inferred rather than observed. By treating polybutadiene with a difluorocarbene source, we embedded gem-difluorocyclopropanes (gDFCs) along the polymer backbone. We report that mechanochemical activation(More)
The molecular weight of a polymer determines key optoelectronic device characteristics, such as internal morphology and charge transport. Therefore, it is important to ensure that polymer deposition techniques do not significantly alter the native polymer molecular weight. This work addresses polymers deposited by resonant infrared matrix-assisted pulsed(More)
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