Jennifer L Nehring

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Reaction of Fe(2)(mu-S(2)C(3)H(6))(CO)(6) (1) with 2 equiv of t-BuNC affords a disubstitued species Fe(2)(mu-S(2)C(3)H(6))(CN-t-Bu)(2)(CO)(4) (2). The structure of 2 has been determined by X-ray crystallography, which shows that in the solid state both isonitrile ligands are cis to sulfur. In solution, NMR and IR spectroscopy suggest that multiple isomers(More)
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